Chemical evolution in the high arsenic groundwater of the Huhhot basin (Inner Mongolia,PR China) and its difference from the western Bengal basin (India)     

Abhijit Mukherjee  Prosun Bhattacharya  Fei Shi  Alan E. Fryar  Arun B. Mukherjee  Zheng M. Xie  Gunnar Jacks  Jochen Bundschuh 《Applied Geochemistry》2009

Elevated As concentrations in groundwater of the Huhhot basin (HB), Inner Mongolia, China, and the western Bengal basin (WBB), India, have been known for decades. However, few studies have been performed to comprehend the processes controlling overall groundwater chemistry in the HB. In this study, the controls on solute chemistry in the HB have been interpreted and compared with the well-studied WBB, which has a very different climate, physiography, lithology, and aquifer characteristics than the HB. In general, there are marked differences in solute chemistry between HB and WBB groundwaters. Stable isotopic signatures indicate meteoric recharge in the HB in a colder climate, distant from the source of moisture, in comparison to the warm, humid WBB. The major-ion composition of the moderately reducing HB groundwater is dominated by a mixed-ion (Ca–Na–HCO₃–Cl) hydrochemical facies with an evolutionary trend along the regional hydraulic gradient. Molar ratios and thermodynamic calculations show that HB groundwater has not been affected by cation exchange, but is dominated by weathering of feldspars (allitization) and equilibrium with gibbsite and anorthite. Mineral weathering and mobilization of As could occur as recharging water flows through fractured, argillaceous, metamorphic or volcanic rocks in the adjoining mountain-front areas, and deposits solutes near the center of the basin. In contrast, WBB groundwater is Ca–HCO₃-dominated, indicative of calcite weathering, with some cation exchange and silicate weathering (monosiallitization).  相似文献   

Determination of Ocean Wave Period from Altimeter Data Using Wave-Age Concept     

Jignesh Kshatriya  Abhijit Sarkar  Raj Kumar 《Marine Geodesy》2013,36(1):71-79

This study makes use of the concept of wave age in estimating ocean wave period from space borne altimeter measurements of backscattering coefficient and significant wave height. Introduction of wave age allowed better accounting of the difference between swells and wind waves. Using two years (1998 and 1999) data of TOPEX/Poseidon altimeter and ocean data buoy observations in the Indian Ocean, coefficients were generated for wave period, which were subsequently tested against data for the years 2000 and 2001. The results showed the wave period accuracy to be of the order of 0.6 sec (against 1.3 sec obtained with the semiempirical approach, reported earlier).  相似文献   

Inter-Comparison of Numerical Model Generated Surface Winds with QuikSCAT Winds over the Indian Ocean     

Sanjib K. Deb  Suchandra A. Bhowmick  Raj Kumar  Abhijit Sarkar 《Marine Geodesy》2013,36(4):391-408

The accurate surface wind in the equatorial Indian Ocean is crucial for modeling ocean circulation over this region. In this study, the surface wind analysis generated at the European Center for Medium Range Weather Forecasts (ECMWF) and the National Centers for Environmental Prediction (NCEP) are compared with NASA QuikSCAT satellite derived Level2B (swath level) and Level3 (gridded) surface winds for the year 2005. It is observed that the ECMWF winds exhibit speed bias of 1.5 m/s with respect to QuikSCAT Level3 in the southern equatorial Indian Ocean. The NCEP winds are found to exhibit speed bias (1.0–1.5 m/s) in the southern equatorial Indian Ocean specifically during January–February 2005. The biases are also observed in the analysis when compared with Level2B product as well; however, it is less in comparison to Level3 products. The amplitude of daily variations of both ECMWF and NCEP wind speed in Bay of Bengal and parts of the Arabian Sea is about 80% of that in QuikSCAT, while in the equatorial Indian Ocean it is about 60% of that of QuikSCAT.  相似文献   

Application of data assimilation for improving forecast of water levels and residual currents in Singapore regional waters     

Rama Rao Karri  Abhijit Badwe  Xuan Wang  Ghada El Serafy  Julius Sumihar  Vladan Babovic  Herman Gerritsen 《Ocean Dynamics》2013,63(1):43-61

Hydrodynamic models are commonly used for predicting water levels and currents in the deep ocean, ocean margins and shelf seas. Their accuracy is typically limited by factors, such as the complexity of the coastal geometry and bathymetry, plus the uncertainty in the flow forcing (deep ocean tide, winds and pressure). In Southeast Asian waters with its strongly hydrodynamic characteristics, the lack of detailed marine observations (bathymetry and tides) for model validation is an additional factor limiting flow representation. This paper deals with the application of ensemble Kalman filter (EnKF)-based data assimilation with the purpose of improving the deterministic model forecast. The efficacy of the EnKF is analysed via a twin experiment conducted with the 2D barotropic Singapore regional model. The results show that the applied data assimilation can improve the forecasts significantly in this complex flow regime.  相似文献   

Water wave diffraction by a surface-piercing floating compound porous cylinder in finite depth     

Abhijit Sarkar 《地球物理与天体物理流体动力学》2013,107(4):348-376

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Geochemical exploration for hydrocarbons in the soils of southeast of Krishna-Godavari Basin, Andhra Pradesh     

M. Lakshmi  M. A. Rasheed  T. Madhavi  B. Rajeswara Reddy  M. S. Kalpana  D. J. Patil  A. M. Dayal 《Journal of the Geological Society of India》2012,80(5):641-652

Surface adsorbed gas surveys and geo-microbiological surveys are known techniques of petroleum exploration and aim towards risk reduction in exploration by way of identifying the areas warm with hydrocarbons and to establish intense exploration priorities amongst the identified warm areas. The present investigation aims to explore correlation between the adsorbed gas distribution pattern with the distribution of the counts of methane, ethane, propane and butane microbial oxidizers in the sub soil samples to establish the role of the latter in identifying the upward migration of hydrocarbons especially in the known petroliferous Krishna-Godavari Basin, India. A total of 135 soil samples were collected near oil and gas fields of Tatipaka, Pasarlapudi areas of Krishna Godavari Basin, Andhra Pradesh. The soil samples were collected from a depth of 2?C2.5 m. The samples collected, were analyzed for indicator hydrocarbon oxidizing bacteria, adsorbed light gaseous hydrocarbons and carbon isotopes (??¹³C_methane). The microbial prospecting studies showed the presence of high bacterial population for methane (3.94 × 10⁵ cfu/gm), ethane (3.85 × 10⁵ cfu/gm), propane (4.85 × 10⁵ cfu/gm) and butane oxidizing bacteria (3.63 × 10⁵ cfu/gm) in soil samples indicating microseepage of hydrocarbons. The light gaseous hydrocarbon analysis showed 83 ppb, 92 ppb, 134 ppb, 187 ppb and 316 ppb of C₁, C₂, C₃, nC₄ and nC₅, respectively, and the carbon isotopic composition of ??¹³C₁ of the samples ranged between ? 36.6 ?? to ?22.7?? (Pee Dee Belemnite) values, which presents convincing evidence that the adsorbed soil gases collected from these sediments are of thermogenic origin. Geo-microbial prospecting method and adsorbed soil gas and carbon isotope studies have shown good correlation with existing oil/ gas fields of K.G basin. Microbial surveys indicating microseepage of hydrocarbons can, therefore, independently precede other geochemical and geophysical surveys to delineate areas warm with hydrocarbons and mapped microbiological anomalies may provide focus for locales of hydrocarbon accumulation in the K.G basin.  相似文献   

Spatio-Temporal Coherence Based Technique for Near-Real Time Sea-Ice Identification from Scatterometer Data     

Sandip R. Oza  R. K. K. Singh  N. K. Vyas  B. S. Gohil  Abhijit Sarkar 《Journal of the Indian Society of Remote Sensing》2011,39(2):147-152

The identification of sea-ice has frequently been cited as one of the most important tasks for deriving the sea-ice parameters and to avoid erroneous retrieval of wind vector over sea-ice infested oceans using space-borne scatterometer data. Discrimination between sea-ice and ocean is ambiguous under the high wind and/or thin/scattered ice conditions. The pre-launch technique developed for Oceansat-2, utilizes the dual-polarized QuikSCAT scatterometer data by using the spatio-temporal coherence properties of sea ice in addition to backscatter coefficient and the Active Polarization Ratio. Results were compared with the operational sea-ice products from National Snow and Ice Data Center. The threshold API value of −0.025 was found optimum for sea-ice and ocean discrimination. The overall sea-ice identification accuracy achieved was of the order of 95 per cent, ranging from 92.5% (during December in Southern Hemisphere) to 98% (during March in Northern Hemisphere). The applicability of the algorithm for both the Arctic as well as Antarctic makes it suitable for its operational use with the Oceansat-2 scatterometer data.  相似文献   

Stable carbon isotope geochemistry of adsorbed alkane gases in near-surface soils of the Saurashtra Basin,India     

Devleena Mani  D.J. Patil  A.M. Dayal 《Chemical Geology》2011,280(1-2):144-153

The stable carbon isotopic compositions of light hydrocarbon gases adsorbed in near-surface soil and sediments from the Saurashtra basin were characterized for their origin and maturity. Saurashtra is considered geologically prospective for oil and gas reserves; however, a major part of the basin is covered by the Deccan Traps, hindering the exploration of Mesozoic hydrocarbon targets. Surface geochemical prospecting, based on micro-seepage of hydrocarbons from subsurface accumulations, could be advantageous in such areas. In light of this, 150 soil samples were collected from the northwestern part of Saurashtra, around the Jamnagar area, where a thick sedimentary sequence of about 2–3 km exists under 1–1.5 km of Deccan basalt. The concentration of acid desorbed alkane gases from soil samples was found to vary (in ppb) as: methane (C₁) = 3–518; ethane (C₂) = 0–430; propane (C₃) = 0–331; i-butane (iC₄) = 0–297; n-butane (nC₄) = 2–116; i-pentane (iC₅) = 0–31 and n-pentane (nC₅) = 0–23, respectively.Fifteen samples with high concentrations of alkane gases were measured for their δ¹³C₁; δ¹³C₂ and δ¹³C₃ compositions using gas chromatography–combustion-isotope ratio mass spectrometry (GC–C-IRMS). The values for methane varied from ? 27 to ? 45.4‰, ethane from ? 20.9 to ? 27.6‰, and propane from ? 20.4 to ? 29.1‰ versus the Vienna PeeDee Belemnite (VPDB). The carbon isotope ratio distribution pattern represents isotopic characteristics pertaining to hydrocarbon gases derived from thermogenic sources. Comparisons of carbon isotopic signatures and compositional variations with the standard carbon isotopic models suggest that hydrocarbon gases found in the shallow depths of the study area are not of bacterial origin but are formed thermally from deeply buried organic matter, likely to be mainly a terrestrial source rock with a partial contribution from a marine source. These gases may have migrated to the near-surface environment, where they represent an admixture of thermally generated hydrocarbon gases from mixed sources and maturity. The maturity scale (δ¹³C versus Log Ro %) applied to the surface sediment samples of the Jamnagar area indicated the source material to be capable of generating oil and gas. The detection of thermogenic alkane gases in near-surface sediments offers the possibility of hydrocarbons at depth in Saurashtra.  相似文献   

A reinterpretation of two chertbreccias from the Proterozoic basins of India     

Vivek S. Kale  Shilpa Patil Pillai 《Journal of the Geological Society of India》2011,78(5):429-445

Several horizons of a unique lithotype called “chertbreccia” are interbedded within the Proterozoic platform sediments of the Peninsular India. These cherty rocks with brecciated texture appearing as blocky masses were earlier diversely interpreted as being products of disparate processes such as fault-zone breccias, collapse breccias, and so on. Two of these horizons, one from the Kaladgi Basin (Dharwar Craton) and the other from the Dhar Forest Inlier of the Vindhyanchal Basin (Bundelkhand — Aravalli Craton) are compared in context of their geological setting, field relations and petrological constitution. A model of the mode of development of these peculiar rocks is reconstructed, taking into account their characters and limitations of previous interpretations. They are interpreted as transported debris deposits of syntectonogenic material released during the episodic activity of the growth faults of the Kaladgi and Vindhyanchal Basins that was diagenetically silicified.  相似文献   

Soil Iodine Determination in Deccan Syneclise,India: Implications for Near Surface Geochemical Hydrocarbon Prospecting     

Devleena Mani  T. Satish Kumar  M. A. Rasheed  D. J. Patil  A. M. Dayal  T. Gnaneshwar Rao  V. Balaram 《Natural Resources Research》2011,20(1):75-88

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r ² < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.  相似文献